XLI.—The hydration of ions and metal overvoltage
نویسندگان
چکیده
منابع مشابه
application and construction of carbon paste modified electrodes developed for determination of metal ions in some real samples
ساخت الکترودهاِی اصلاح شده ِیکِی از چالشهاِی همِیشگِی در دانش شیمِی بوِیژه شیمِی تجزیه مِی باشد ،که با در نظر گرفتن سادگِی ساخت، کاربردی بودن و ارزان بودن روش مِی توان به باارزش بودن چنِین سنسورهاِی پِی برد.آنچه که در ادامه آورده شده به ساخت و کاربرد الکترودهاِی اصلاح شده با استفاده از نانو ذرات در اندازه گِیرِی ولتامترِی آهن وکادمِیم اشاره دارد. کار اول اختصاص دارد به ساخت الکترود خمِیر کربن اصلاح شده با لِیگاند داِ...
15 صفحه اولOn the hydration of ions
This report will concentrate on ions which are produced in nuclear power reactors and/or which are of special interest because of their small radius and/or their high charges, leading to hydrolysis. Mainly the results of Molecular Dynamics simulations will be discussed as they are able to provide a comprehensive and consistent description of the structural and dynamical properties of the water ...
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With the final goal set at theoretical elucidation of experimentally observed isotope salt effects, molecular orbital calculations were performed to estimate the 18 O/16 O and D/H isotopic reduced partition function ratios (RPFRs) of water molecules around lithium, sodium, and potassium ions. As model water molecules in the ith hydration sphere of the cation in aqueous solutions containing that...
متن کاملA Study of the Hydration of the Alkali Metal Ions in Aqueous Solution
The hydration of the alkali metal ions in aqueous solution has been studied by large angle X-ray scattering (LAXS) and double difference infrared spectroscopy (DDIR). The structures of the dimethyl sulfoxide solvated alkali metal ions in solution have been determined to support the studies in aqueous solution. The results of the LAXS and DDIR measurements show that the sodium, potassium, rubidi...
متن کاملTwo-dimensional hydration shells of alkali metal ions at a hydrophobic surface.
We study the hydration shell formation of alkali metal ions at a graphite surface. Two-dimensional shell structures are found in the initial stage of hydration, in contrast to the three-dimensional structures in bulk water and clusters. Comparison of vibrational spectra with experiments identifies the shell structures and the thermally induced transition from the first to the second shell. We a...
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ژورنال
عنوان ژورنال: J. Chem. Soc., Trans.
سال: 1917
ISSN: 0368-1645
DOI: 10.1039/ct9171100470